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(theta)-benzenemethanamin

  • Chemical raw materials, non-pharmaceuticals.
  • Product Name: (theta)-benzenemethanamin
  • CasNo: 3886-69-9
  • Purity:
  • Appearance: Colorless to light yellow liqui

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CasNo: 3886-69-9

Molecular Formula: C8H11N

Appearance: Colorless to light yellow liqui

Factory Sells Chinese Factory Supply (theta)-benzenemethanamin 3886-69-9 with Lowest Price

  • Molecular Formula:C8H11N
  • Molecular Weight:121.182
  • Appearance/Colour:Colorless to light yellow liqui 
  • Vapor Pressure:0.5 mm Hg ( 20 °C) 
  • Melting Point:-10 °C 
  • Refractive Index:1.5260 
  • Boiling Point:183 °C at 760 mmHg 
  • PKA:9.04±0.10(Predicted) 
  • Flash Point:75.8 °C 
  • PSA:26.02000 
  • Density:0.956 g/cm3 
  • LogP:2.40660 

(R)-(+)-1-Phenylethylamine(Cas 3886-69-9) Usage

Flammability and Explosibility

Nonflammable

Purification Methods

Dissolve the amine in toluene, dry over NaOH and distil; fraction boiling at 187-188o/atm is collected. Store it under N2 to avoid forming the carbamate and urea. Similarly for the S-(-) enantiomer [2627-86-3]. [Ingersoll Org Synth Coll Vol II 503 1943, Robinson & Snyder Org Synth Coll Vol III 717 1955, Beilstein 12 IV 2424, 2425.]

Categories

(1R)-1-Phenylethanamine belongs to the category of chiral amines and is commonly used in chiral resolutions.

Uses and Mechanism of Action

(1R)-1-Phenylethanamine is utilized in chiral resolutions, particularly in crystallization processes to obtain diastereomeric salts with excellent diastereoselectivity. In crystallization processes, (1R)-1-Phenylethanamine interacts with other compounds, such as cis-permethric acid, to form diastereomeric salts through specific intermolecular interactions, resulting in the separation of enantiomers.

Definition

ChEBI: The (R)-enantiomer of 1-phenylethanamine.

General Description

(R)-(+)-α-Methylbenzylamine is a chiral amine.

InChI:InChI=1/C8H11N/c1-7(9)8-5-3-2-4-6-8/h2-7H,9H2,1H3/p+1/t7-/m1/s1

3886-69-9 Relevant articles

Synthesis and reactivity towards carbon monoxide of an optically active endo five-membered ortho-cyclopalladated imine: X-ray molecular structure of trans-(μ-Cl)2[Pd(κ2-C,N-(R)-C6H4-CH{double bond, long}N-CHMe-Ph)]2

Albert, Joan,D'Andrea, Luci?a,Granell, Jaume,Tavera, Raquel,Font-Bardia, Mercè,Solans, Xavier

, p. 3070 - 3080 (2007)

(R)-1-Phenylethyl-benzylidene-amine (1) ...

Crystallization-based resolution of 1,4-benzodioxane-2-carboxylic acid enantiomers via diastereomeric 1-phenylethylamides

Fumagalli, Laura,Bolchi, Cristiano,Bavo, Francesco,Pallavicini, Marco

, p. 2009 - 2011 (2016)

Unlike the diastereomeric 1-phenylethyla...

Determination of absolute configurations of amines and amino acids using nonchiral derivatizing agents (NCDA) and deuterium NMR.

Chalard,Bertrand,Canet,Thery,Remuson,Jeminet

, p. 2431 - 2434 (2000)

Enantiomeric analysis and empirical dete...

Enantioselective Cascade Biocatalysis for Deracemization of Racemic β-Amino Alcohols to Enantiopure (S)-β-Amino Alcohols by Employing Cyclohexylamine Oxidase and ω-Transaminase

Zhang, Jian-Dong,Chang, Ya-Wen,Dong, Rui,Yang, Xiao-Xiao,Gao, Li-Li,Li, Jing,Huang, Shuang-Ping,Guo, Xing-Mei,Zhang, Chao-Feng,Chang, Hong-Hong

, p. 124 - 128 (2020/09/21)

Optically active β-amino alcohols are ve...

Highly Stable Zr(IV)-Based Metal-Organic Frameworks for Chiral Separation in Reversed-Phase Liquid Chromatography

Jiang, Hong,Yang, Kuiwei,Zhao, Xiangxiang,Zhang, Wenqiang,Liu, Yan,Jiang, Jianwen,Cui, Yong

supporting information, p. 390 - 398 (2021/01/13)

Separation of racemic mixtures is of gre...

Rational Design of Chiral Nanohelices from Self-Assembly of Meso-tetrakis (4-Carboxyphenyl) Porphyrin-Amino Acid Conjugates

Yang, Xuejiao,Shen, Yuhe,Liu, Jiayu,Wang, Yuefei,Qi, Wei,Su, Rongxin,He, Zhimin

, p. 13067 - 13074 (2021/11/16)

In this article, meso-tetrakis (4-carbox...

Generation of Oxidoreductases with Dual Alcohol Dehydrogenase and Amine Dehydrogenase Activity

Tseliou, Vasilis,Schilder, Don,Masman, Marcelo F.,Knaus, Tanja,Mutti, Francesco G.

supporting information, p. 3315 - 3325 (2020/12/11)

The l-lysine-?-dehydrogenase (LysEDH) fr...

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