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CasNo: 7683-64-9
Molecular Formula: C30H50
Appearance: light yellow liquid
Definition |
squalene: An intermediate compoundformed in the synthesis ofcholesterol; it is a hydrocarbon containing30 carbon atoms. The immediateoxidation of squalene tosqualene 2,3-epoxide is the last commonstep in the synthesis of sterolsin animals, plants, and fungi. |
InChI:InChI=1/C30H50/c1-25(2)15-11-19-29(7)23-13-21-27(5)17-9-10-18-28(6)22-14-24-30(8)20-12-16-26(3)4/h15-18,23-24H,9-14,19-22H2,1-8H3/b27-17+,28-18+,29-23+,30-24+
Complexation of primary allylic chloride...
Farnesol
(6E,10E,14E,18E)-2,6,10,15,19,23-Hexamethyl-tetracosa-2,6,10,14,18,22-hexaene
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps
1: 60 percent / methanesulfonyl chloride, pyridine / pentane
2: 1.) Pd2(dba)3CHCl3 / 1.) benzene; 2.) irradiation, acetonitrile
With
pyridine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; methanesulfonyl chloride;
In
pentane;
|
1-chloro-3,7,11-trimethyldodeca-2,6,10-triene
(6E,10E,14E,18E)-2,6,10,15,19,23-Hexamethyl-tetracosa-2,6,10,14,18,22-hexaene
Conditions | Yield |
---|---|
With
tris(dibenzylideneacetone)dipalladium(0) chloroform complex;
Multistep reaction;
1.) benzene; 2.) irradiation, acetonitrile;
|
1-chloro-3,7,11-trimethyldodeca-2,6,10-triene
(2E,6E)-farnesyl chloride
Farnesol
2,6,10,15,19,23-hexamethyltetracosane